Nigerian delegates are ready to take part in the first phase, which will begin across the continent next month.
Nigeria Professional Football League champions Aqua United will face Algeria League 1 champion CR Bellozdad in the first round of the preliminary round of the Kiev Champions League.
The Promise Keepers won their first league title earlier this month and will be aiming to qualify for the group stage of the continental tournament when the qualifiers begin in September.
Kennedy Boboy’s men will host the Algerian club for the first leg of their trip to Alteria at the Godsville Acapabio Stadium.
Rivers United, who finished runners-up in the 2020-21 NPFL season, are the country’s second representative in the Champions League and will face Tanzania’s Young African Sports Club.
Last season, the Pride of the Rivers failed in the Kiev Confederations Cup qualifiers as they were knocked out on penalties by rival Anemba after a 1-1 aggregate draw.
The first leg of the Kiev Champions League qualifiers will take place between September 10-12, while the reverse fixtures are scheduled for September 17-19.